Handbook on the Physics and Chemistry of Rare Earths

Handbook on the Physics and Chemistry of Rare Earths

by Karl A. Gschneidner B.S. University of Detroit 1952 Ph.D. Iowa State University 1957, Jean-Claude G. Bunzli, Vitalij K. Pecharsky
ISBN-10:
0444532218
ISBN-13:
9780444532213
Pub. Date:
02/13/2009
Publisher:
Elsevier Science
ISBN-10:
0444532218
ISBN-13:
9780444532213
Pub. Date:
02/13/2009
Publisher:
Elsevier Science
Handbook on the Physics and Chemistry of Rare Earths

Handbook on the Physics and Chemistry of Rare Earths

by Karl A. Gschneidner B.S. University of Detroit 1952 Ph.D. Iowa State University 1957, Jean-Claude G. Bunzli, Vitalij K. Pecharsky
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Overview

The first chapter (241) in this volume of the Handbook on the Physics and Chemistry of Rare Earths gives a theoretical overview of the dual nature of 4f states in the lanthanides, which may either be part of the valence states or be inert and form part of the core. First principles theory is supported by relevant experimental data, thus providing a coherent picture of the present state-of-the-art of this fascinating subject. Chapter 242 is a compilation of temperature-dependent data about crystallography and crystal chemistry of over a hundred of aluminates (RAlO3) and gallates (RGaO3) and their solid solutions. The reader should find a systematic analysis of structures and distortions, as well as detailed phase diagrams of numerous RAlO3 – R’AlO3 and RGaO3 – R’GaO3 systems both interesting and useful. The last chapter (243) is focused on the chemistry of polyoxometallolanthanoates – a special class of metal-oxide cluster compounds – which may be considered as models for lanthanide-doped metal-oxide phosphors. This review develops an understanding of molecular mechanisms of energy transfer processes in metal-oxide phosphors, and shows that the oxygen-metal states are involved not only in energy transfer, but also in electron transfer during photoredox reactions, thus making the photochemical design of Mo-blue nano-rings possible.


Product Details

ISBN-13: 9780444532213
Publisher: Elsevier Science
Publication date: 02/13/2009
Series: Handbook on the Physics and Chemistry of Rare Earths , #39
Pages: 416
Product dimensions: 6.50(w) x 9.45(h) x (d)

About the Author

Gschneidner has published over 485 journal articles and chapters in books and edited or written 40 books on the chemistry, materials science, and physics or rare earth materials. He was the founder of the Rare-earth Information Center and served as its Director for 30 years.

Jean-Claude Bünzli (he/him) is an Honorary Professor emeritus at the EPFL where he founded the Laboratory of Lanthanide Supramolecular Chemistry He earned a degree in chemical engineering in 1968 and a PhD in 1971 from the Swiss Federal Institute of Technology, Lausanne (EPFL). After two years at the University of British Columbia as a teaching postdoctoral fellow (photoelectron spectroscopy) and one year at the Swiss Federal Institute of Technology in Zürich (physical organic chemistry) he was appointed in 1974 as assistant-professor at the University of Lausanne. He launched a research program on the coordination and spectroscopic properties of f-elements and was promoted to full professor of inorganic and analytical chemistry in 1980. During 2009-2013 he was also a World Class University professor at Korea University (South Korea) at the WCU Center for Next Generation Photovoltaic Devices. In 2016, he has been appointed as adjunct professor at the Haimen Institute of Science and Technology (Haimen, Jiangsu, P.R. China) which is a satellite campus of Hong Kong Baptist University. His research interests deal with various aspects of luminescent lanthanide coordination and supramolecular compounds, developing luminescent bioprobes and bioconjugates for the detection of cancerous cells with time-resolved microscopy as well as luminescent materials for various photonic applications, including solar energy conversion. In 1989, he founded the European Rare Earths and Actinide Society which coordinates international conferences in the field and for which he is presently acting as president.

V.K. Pecharsky received a combined BSc/MSc degree in Chemistry (1976) and a PhD degree in Inorganic Chemistry (1979) from Lviv State University (now Ivan Franko National University of Lviv) in Ukraine. He held a faculty appointment at the Department of Inorganic Chemistry at Lviv State University between 1979 and 1993, after which he moved to Ames, Iowa, where he became a staff member at the U.S. Department of Energy Ames Laboratory. In 1998 he accepted a faculty position at the Department of Materials Science and Engineering at Iowa State University, while remaining associated with Ames Laboratory. He was named an Anson Marston Distinguished Professor of Engineering in 2006. He also serves as a Faculty Scientists, Field Work Project Leader, and Group Leader at Ames Laboratory.
While in Lviv, V. Pecharsky was studying phase relationships and crystallography of ternary intermetallic compounds containing rare earths. After moving to Ames his research interests shifted to examining composition-structure-physical property relationship of rare-earth intermetallic compounds. Together with Karl Gschneidner, Jr., he discovered a new class of materials that exhibit the giant magnetocaloric effect in 1997, triggering worldwide interest in caloric materials and caloric cooling, which promises to become an energy-efficient, environmentally-friendly alternative to conventional vapor-compression approach. Today his research interest include synthesis, structure, experimental thermodynamics, physical and chemical properties of intermetallic compounds containing rare-earth metals; anomalous behavior of 4f-electron systems; magnetostructural phase transformations; physical properties of ultra-pure rare earth metals; caloric materials and systems; hydrogen storage materials; mechanochemistry, mechanically induced solid-state reactions and mechanochemical transformations.
He organized the 28th Rare Earth Research Conference in Ames, Iowa in 2017. He serves as co-editor of the Handbook on the Physics and Chemistry of Rare Earths and senior editor of the Journal of Alloys and Compounds. He has published over 500 WOS papers (>22 600 cites, h factor = 60).

Table of Contents

Preface. Electronic excitation in atomic species (J.-P. Connerade, R.C. Karnatak). Simple and complex halides (G. Meyer, M.S. Wickleder). Solid electrolytes (R.V. Kumar, H. Iwahara). Activated thermoluminescent (TL) dosimeters and related radiation detectors (A. Halperin). Analytical separations of the lanthanides: basic chemistry and methods (K.L. Nash, M.P. Jensen). Author index. Subject index.
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